There are two scenes in the movie where Banner calls out to Hulk and Hulk denies him. These events happens after the first Hulk fight where Loki proclaims "We have a Hulk".
One is in New York during the fight with the children of Thanos. The other is in Wakanda.
When Banner called out to Hulk, he simply responds with a curt “Nooo”. What could be the reason?