When LMD Fitz and Jemma check the base cam in episode 14 it shows all 4 (Daisy, Mace, Mack and Coulson) as LMDs, but later Daisy is not one.
Another question. how did they bring that many Daisy replicas into the HQ?
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While it's true that Simmons says "all of them" when asked about the LMD's, the on-screen report is SLIGHTLY different.
Notice that text on the display:
S[?]Q TRL 922 MEMORY BUFFER - COMPILE ALL REPORT TOTALS:  LIFE MODEL DECOYS DETECTED
The display is reporting the cumulative total of LMDs that went past the sensor - not the number of LMDS on the screen at the moment.
We learn in the following episode that while Daisy is not an LMD, Fitz is - bringing the count of LMDs that went through the sensor to four.