I found an article that said that the first appearance was in season 3, but Walt wore it in season 1 when he and Jesse met up with Tuco in the parking lot. I don't remember this being the first appearance, because doesn't he first look at it in his car or something?
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1I read that his putting on the hat in season 3 marks the emergence of Heisenberg, so it's a first in that respect.– MJ6Oct 9, 2013 at 2:13
1 Answer
That was indeed the hat's first appearance. Season 1 episode 7 "A No-Rough-Stuff-Type Deal". Jesse even comments on it.
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